Chapter 8

Chapter 8

Problem 8-1
2-Methyl-2-butene and 2-methyl-1-butene
Problem 8-3
trans-1,2-Dichloro-1,2-dimethylcyclohexane
Problem 8-5
trans-2-Bromocyclopentanol
Problem 8-6
Markovnikov
Problem 8-7
(a)
2-Pentanol
(b)
2-Methyl-2-pentanol
Problem 8-8
(a)
Oxymercuration of 2-methyl-1-hexene or 2-methyl-2-hexene
(b)
Oxymercuration of cyclohexylethylene or hydroboration of ethylidenecyclohexane
Problem 8-10
(a)
3-Methyl-1-butene
(b)
2-Methyl-2-butene
(c)
Methylenecyclohexane
Problem 8-12
(a)
2-Methylpentane
(b)
1,1-Dimethylcyclopentane
(c)
tert-Butylcyclohexane
Problem 8-14
(a)
1-Methylcyclohexene
(b)
2-Methyl-2-pentene
(c)
1,3-Butadiene
Problem 8-15
(a)
CH3COCH2CH2CH2CH2CO2H
(b)
CH3COCH2CH2CH2CH2CHO
Problem 8-16
(a)
2-Methylpropene
(b)
3-Hexene
Problem 8-18
(a)
H2C ═ CHOCH3
(b)
ClCH ═ CHCl
Problem 8-20

An optically inactive, non-50 : 50 mixture of two racemic pairs: (2R,4R) + (2S,4S) and (2R,4S) + (2S,4R)

Problem 8-21
Non-50 : 50 mixture of two racemic pairs: (1S,3R) + (1R,3S) and (1S,3S) + (1R,3R)