Key Equations

Key Equations

12.2 First law of Thermodynamics: Thermal Energy and Work

ideal gas law PV=NkT PV=NkT
first law of thermodynamics ΔU=Q−W ΔU=Q−W
pressure P= F A P= F A
pressure–volume work W=PΔV W=PΔV

12.3 Second Law of Thermodynamics: Entropy

change in entropy ΔS= Q T ΔS= Q T

12.4 Applications of Thermodynamics: Heat Engines, Heat Pumps, and Refrigerators

thermal efficiency of a heat engine Eff= W Q h Eff= W Q h
work output for a cyclical process W= Q h − Q c W= Q h − Q c